| Segunda Division | 1 | 2013-08-18 | AWAY | Sporting Gijon | 1-0 |
| Segunda Division | 2 | 2013-08-24 | HOME | AD Alcorcon | 0-1 |
| Segunda Division | 3 | 2013-08-31 | AWAY | Hercules Alicante CF | 2-1 |
| Segunda Division | 4 | 2013-09-08 | HOME | CD Mirandes | 0-1 |
| Segunda Division | 5 | 2013-09-15 | AWAY | FC Barcelona B | 2-0 |
| Segunda Division | 6 | 2013-09-21 | HOME | Real Zaragoza | 1-2 |
| Segunda Division | 7 | 2013-09-29 | AWAY | CD Tenerife | 1-0 |
| Segunda Division | 8 | 2013-10-06 | HOME | CD Lugo | 2-0 |
| Segunda Division | 9 | 2013-10-12 | HOME | Recreativo de Huelva | 1-2 |
| Segunda Division | 10 | 2013-10-20 | AWAY | RCD Mallorca | 2-0 |
| Segunda Division | 11 | 2013-10-27 | HOME | SD Ponferradina | 1-1 |
| Segunda Division | 12 | 2013-11-03 | AWAY | Deportivo la Coruna | 2-0 |
| Segunda Division | 13 | 2013-11-10 | HOME | Deportivo Alaves | 1-0 |
| Segunda Division | 14 | 2013-11-17 | AWAY | SD Eibar | 6-0 |
| Segunda Division | 15 | 2013-11-23 | HOME | Numancia CD | 0-0 |
| Segunda Division | 16 | 2013-12-01 | AWAY | Real Jaen CF | 0-1 |
| Segunda Division | 17 | 2013-12-04 | HOME | Girona FC | 3-2 |
| Segunda Division | 18 | 2013-12-14 | AWAY | Las Palmas | 0-2 |
| Segunda Division | 19 | 2013-12-21 | HOME | Cordoba | 3-1 |
| Segunda Division | 20 | 2014-01-04 | AWAY | CD Sabadell | 3-2 |
| Segunda Division | 21 | 2014-01-11 | HOME | Real Murcia | 2-2 |
| Segunda Division | 22 | 2014-01-18 | HOME | Sporting Gijon | 1-2 |
| Segunda Division | 23 | 2014-01-26 | AWAY | AD Alcorcon | 0-2 |
| Segunda Division | 24 | 2014-02-01 | HOME | Hercules Alicante CF | 4-0 |
| Segunda Division | 25 | 2014-02-09 | AWAY | CD Mirandes | 2-1 |
| Segunda Division | 26 | 2014-02-15 | HOME | FC Barcelona B | 3-1 |
| Segunda Division | 27 | 2014-02-23 | AWAY | Real Zaragoza | 0-2 |
| Segunda Division | 28 | 2014-03-01 | HOME | CD Tenerife | 2-2 |
| Segunda Division | 29 | 2014-03-09 | AWAY | CD Lugo | 1-1 |
| Segunda Division | 30 | 2014-03-15 | AWAY | Recreativo de Huelva | 2-3 |
| Segunda Division | 31 | 2014-03-23 | HOME | RCD Mallorca | 1-2 |
| Segunda Division | 32 | 2014-03-29 | AWAY | SD Ponferradina | 0-0 |
| Segunda Division | 33 | 2014-04-05 | HOME | Deportivo la Coruna | 0-2 |
| Segunda Division | 34 | 2014-04-13 | AWAY | Deportivo Alaves | 2-2 |
| Segunda Division | 35 | 2014-04-19 | HOME | SD Eibar | 0-1 |
| Segunda Division | 36 | 2014-04-27 | AWAY | Numancia CD | 0-0 |
| Segunda Division | 37 | 2014-05-04 | HOME | Real Jaen CF | 1-1 |
