| Primera Division | 1 | 1996-09-01 | AWAY | Real Zaragoza | 2-2 |
| Primera Division | 2 | 1996-09-07 | HOME | CD Tenerife | 0-1 |
| Primera Division | 3 | 1996-09-15 | AWAY | SD Compostela | 1-2 |
| Primera Division | 4 | 1996-09-21 | HOME | Atletico de Madrid | 0-3 |
| Primera Division | 5 | 1996-09-29 | HOME | Sevilla FC | 2-0 |
| Primera Division | 6 | 1996-10-02 | AWAY | Valencia CF | 0-1 |
| Primera Division | 7 | 1996-10-13 | HOME | Sporting Gijon | 0-2 |
| Primera Division | 8 | 1996-10-20 | AWAY | FC Barcelona | 8-0 |
| Primera Division | 9 | 1996-10-23 | HOME | Real Valladolid | 0-1 |
| Primera Division | 10 | 1996-10-27 | AWAY | Athletic de Bilbao | 6-0 |
| Primera Division | 11 | 1996-11-03 | HOME | CF Extremadura | 0-0 |
| Primera Division | 12 | 1996-11-10 | AWAY | Real Madrid | 0-0 |
| Primera Division | 13 | 1996-11-17 | HOME | Celta Vigo | 0-3 |
| Primera Division | 14 | 1996-11-24 | AWAY | Deportivo la Coruna | 4-1 |
| Primera Division | 15 | 1996-12-01 | HOME | Hercules Alicante CF | 3-2 |
| Primera Division | 16 | 1996-12-08 | AWAY | Real Betis Sevilla | 5-1 |
| Primera Division | 17 | 1996-12-22 | HOME | Rayo Vallecano | 0-2 |
| Primera Division | 18 | 1997-01-05 | AWAY | Real Oviedo | 2-1 |
| Primera Division | 19 | 1997-01-12 | HOME | Espanyol Barcelona | 1-0 |
| Primera Division | 20 | 1997-01-19 | AWAY | Racing de Santander | 2-1 |
| Primera Division | 21 | 1997-01-26 | HOME | Real Sociedad | 1-0 |
| Primera Division | 21 | 1997-02-02 | HOME | Real Zaragoza | 1-2 |
| Primera Division | 23 | 1997-02-09 | AWAY | CD Tenerife | 2-0 |
| Primera Division | 24 | 1997-02-16 | HOME | SD Compostela | 1-1 |
| Primera Division | 25 | 1997-02-19 | AWAY | Atletico de Madrid | 2-0 |
| Primera Division | 26 | 1997-02-23 | AWAY | Sevilla FC | 1-4 |
| Primera Division | 26 | 1997-03-01 | HOME | Valencia CF | 2-1 |
| Primera Division | 28 | 1997-03-09 | AWAY | Sporting Gijon | 2-0 |
| Primera Division | 29 | 1997-03-16 | HOME | FC Barcelona | 0-1 |
| Primera Division | 30 | 1997-03-23 | AWAY | Real Valladolid | 2-1 |
| Primera Division | 31 | 1997-03-30 | HOME | Athletic de Bilbao | 1-4 |
| Primera Division | 32 | 1997-04-06 | AWAY | CF Extremadura | 3-0 |
| Primera Division | 33 | 1997-04-13 | HOME | Real Madrid | 0-2 |
| Primera Division | 34 | 1997-04-16 | AWAY | Celta Vigo | 4-0 |
| Primera Division | 35 | 1997-04-20 | HOME | Deportivo la Coruna | 1-2 |
| Primera Division | 36 | 1997-05-04 | AWAY | Hercules Alicante CF | 1-0 |
| Primera Division | 37 | 1997-05-11 | HOME | Real Betis Sevilla | 2-1 |
| Primera Division | 38 | 1997-05-18 | AWAY | Rayo Vallecano | 1-0 |
| Primera Division | 39 | 1997-05-25 | HOME | Real Oviedo | 1-1 |
| Primera Division | 40 | 1997-06-01 | AWAY | Espanyol Barcelona | 5-1 |
| Primera Division | 41 | 1997-06-15 | HOME | Racing de Santander | 1-1 |
| Primera Division | 42 | 1997-06-22 | AWAY | Real Sociedad | 2-1 |
